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Re: Yellowing of radioactive lens elements....Re: [OM] 55/1.2

Subject: Re: Yellowing of radioactive lens elements....Re: [OM] 55/1.2
From: whunter <whunterjr@xxxxxxxx>
Date: Sat, 9 Aug 2003 16:09:11 -0400

On Saturday, August 9, 2003, at 12:15  PM, Thomas Haegin wrote:

As I understand the discussion so far, some people's
early lenses are yellowed, but other were spared the
problem. What would cause one Zuiko to turn yellow but
not the other one?

I would expect radioactive decay should occur in all
of them as a function of time only rather than
external things like environment or geographic region
etc. where it was kept.

Ahhhhh Ha...... Exactly!!!! Just posted re this fundamental issue. ONE: degradation is primarily in the organic binder substrates of the coating NOT the inorganic matrix of the glass. TWO: whether induced by ionizing radiation of 'radioactive decay', HEAT, cosmic radiation, etc., you see the effects of degradation in the same end results. Given a constant level of ionizing radiation (UV, radioactive, cosmic, visible light spectrum, whatever......) the degradation rate of the coating will vary greatly depending on ambient temperature AND HUMIDITY. All of this is additive. As you appropriately remind, the differing degradation of the same lens reflects changes in additive contributions from the environment. Further, since the exterior of the lens ( the coating surface) has greatest exposure, virtually all of the observed changes are limited to that molecular level, NOT the glass.
Enuff....
Bill Hunter


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